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Nickel-catalyzed difunctionalization of unactivated alkenes initiated by unstabilized enolates
This report demonstrates the possibility of a nickel-catalyzed difunctionalization of unactivated alkenes initiated by an unstabilized enolate nucleophile. The process tolerates a diverse range of electrophiles, including aryl, heteroaryl, alkenyl, and amino electrophiles. An electron-deficient phosphine ligand and a tetrabutylammonium salt additive were crucial for promoting efficient vicinal difunctionalization.
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Reference£º
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem