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Photochromic derivatives of 5-alkyl-2-(1,3,4-oxadiazol-2-yl)thiophenes have been synthesized for the first time. Their photochromic and fluorescent properties have been studied.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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The invention discloses a photochromic bis(N-ethyl-1,8-naphthalimide)amine-benzothiophene hybrid type perfluorocyclopentene compound, and a synthetic method and application thereof. The photochromic material keeps good photochromic performance in solutions, and has extremely good chemical and heat stability, extremely good sensitivity and other superior performances when being in a ring-opened state (a colorless state) and a ring-closed state (a color appearance state), is applicable to fluorescence detection, fluorescence-controlled switches, high-density holographic optical storage, dual-control fluorescence molecule switches, pH chemical sensors, metal ion chemical sensors and the like, and is wide in application prospect.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Cross-linked liquid-crystalline (LC) polymers with a mesomorphic diarylethene were prepared to demonstrate a versatile strategy for cross-linked photochromic LC polymers as photomobile materials. Upon exposure to UV light to cause photocyclization of the diarylethene chromophore, the cross-linked polymer films bend toward an actinic light source. By irradiation with visible light to cause a closed-ring to open-ring isomerization, the bent films revert to the initial flat state. Without visible-light irradiation, the bent films remain bent even at 120 8C, indicating high thermal stability of the cross-linked diarylethene LC polymers.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. The reactant in an enzyme-catalyzed reaction is called a substrate. Computed Properties of C9H7BrS, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 10243-15-9, Name is 3-Bromo-2-methylbenzo[b]thiophene, molecular formula is C9H7BrS

[A] is colored by UV irradiation rapidly, colored heat fading rate control compound. (1) Of a formula [solution], a diarylethene compound. In the formula, A1 – A4 The, H, halogen, alkyl or the like; X1 X and2 The, S, O, NR (R is H or alkyl) or SO2 , ; Y1 And Y2 The, or N C; R1 And R2 The, H, halogen, alkyl or the like; R3 And R4 The, Y1 Or Y2 C cases where, H, halogen, alkyl or the like, or R5 Or R6 Coupled to the ring structure, Y1 Or Y2 N the case, electron pair; R5 And R6 The, H, halogen, alkyl or the like, or R3 Or R4 Bound form a ring structure. [Drawing] no (by machine translation)

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Reference£º
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Large-scale preparation of aromatic fluorides via electrophilic fluorination with functionalized aryl- or heteroarylmagnesium reagents

Functionalized aryl- or heteroarylmagnesium reagents, prepared from the corresponding bromides or iodides using halogen-magnesium exchange or direct magnesium insertion in the presence of lithium chloride, reacted smoothly with N-fluorobenzenesulfonimide, (PhSO2)2NF, in the mixed solvent (4:1 CH2Cl2-perfluorodecalin) to give the corresponding aromatic fluorides in moderate to good yields. Georg Thieme Verlag Stuttgart · New York.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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COLD MENTHOL RECEPTOR-1 ANTAGONISTS

The invention is directed to TRPM8 antagonists of Formula (I). More specifically, the present invention relates to certain novel compounds, methods for preparing compounds, compositions, intermediates and derivatives thereof and methods for treating TRPM8-mediated disorders. Pharmaceutical and veterinary compositions and methods of treating pain and various other disease states or conditions using compounds of the invention are also described.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Substituent and solvent effects on the fluorescent and photochromic properties of 2-(2-pyridyl)imidazole containing diarylethene derivatives

Five diarylethene derivatives with 2-(2-pyridyl)imidazole as the ethene bridges (PI-BTEs) were synthesized and characterized. The structures and performances of the PI-BTEs (L1-L5) could be modified from not only the thiophene unit, but also the substituent on the imidazole nitrogen. Noteworthily, replacing the thiophene with the benzothiophene, the fatigue resistance is significantly improved, the centre absorption bands of the closed forms shift from 572 nm (L3) to 550 nm (L2), and the colours of the solutions change from pale pink in L3 to red-purple in L2. Additionally, the Stokes shift (Deltanu) values of L3 in various solvents display good linear relationships with the donor number (DN) of the solvents, and the solvent polarity parameter Deltaf.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Sterically hindered diarylethenes with a benzobis(thiadiazole) bridge: Photochemical and kinetic studies

Four rationally designed diarylethenes (DAEs) 1-4 with a benzobis(thiadiazole) bridge are specifically designed for gaining insights into steric effects on photochromic performances. It is shown that, upon increasing steric hindrance, the exchanging rate between two main conformers in the ring-open form gradually slows down, offering the opportunity for isolating photoactive anti-parallel conformers. Impressively, the separated anti-parallel conformer shows high cyclization quantum yields over the unresolved common DAEs. The typical donor-pi-acceptor (D-pi-A) feature in ring-open DAEs 1-4 endows their prominent fluorescence, which can be conveniently modulated by photocyclization. In the ring-closed form, the excess steric hindrance is found to seriously disrupt the thermal bistability, and particularly 3c fades quickly with a half-life of several hours at ambient temperature. In contrast, both 1c and 2c exhibit excellent stability, which originates from the stabilization effects of intramolecular hydrogen bonds. This work demonstrates the steric effects on the photochemical and kinetic behaviors of DAEs, providing a unique approach to develop photochromic DAEs with high photosensitivity.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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5,6,7,12-Tetrahydrodibenz[c,f][1,5]azabismocines: Highly reactive and recoverable organo-bismuth reagents for cross-coupling reactions with Aryl Bromides

Hypervalent organobismuth compounds efficiently couple with aryl bromides in the presence of [Pd(PPh3)4] catalyst. Application of this protocol to a one-pot multi-coupling reaction with bromophenylboronic esters leads to the formation of up to nine bonds in good yields (see scheme).

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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With the Hg2 + And Cys continuous selective asymmetric perfluoro cyclopentene compound and its preparation method and application (by machine translation)

The invention discloses a [1 – [2 – methyl – 3 – benzothienyl], 2 – (2 – methyl – 5 – (4 – phenyl) – (2 – formyl quinoline – 8 – benzothiazolyl) – 3 – thienyl)] full-PVC pentene and its preparation method and application. Preparation method: to benzo thiophene as raw materials, through the iodomethane substituted, brominated, with the perfluoro pentene reaction to generate single substituted perfluoro pentene; to 2 – methyl thiophene as raw materials, bromination, through the n-BuLi and tributyl borate reaction, Stuzki coupling reaction through the end of the with the thiophene ring containing aldehyde group benzene connected, then with ethylene glycol protection after single substituted perfluoro pentene reaction, by reducing dioxiding hydroxy, any change of containing methyl radical bromine, with 8 – hydroxy quinoline – 2 – aldehyde reaction, finally with 2 – amino thiophenol reaction, to obtain the target compound. Prepared by the invention compounds can be used for continuous detection of a specific ion and amino acid, its selectivity is very good. (by machine translation)

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem