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Phosphole-containing pi-systems have emerged as building blocks with enormous potential as electronic materials because of the tunability of the phosphorus center. Among these, asymmetric P-bridged trans-stilbenes are still rare, and here an elegant and efficient synthesis toward such fluorescent molecular frameworks is described. Fine-tuning of the photophysical properties is attempted by enforcing the planarization of the phosphorus tripod and thus increasing the interaction between the phosphorus lone pair and the pi-system. The electronic structure of the pi-conjugated frameworks is analyzed with NMR, UV-vis and fluorescence spectroscopy, and time-dependent density functional theory (TD-DFT) calculations.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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A rapid and efficient synthesis of fused polyphenolic/polymethoxy benzofurans and benzothiophenes that have potential as antitumor agents and components of anti-HIV combination therapy has been achieved.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

Top Picks: new discover of C8H4Br2S

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Metallic catalysts of the general formula (I) and their precursors, suitable for chemo- regio- and stereoselective reactions, derived from ortho-bis-(1-phospholanyl)-heteroarenes. The new catalysts are characterized by the presence of two homomorphic phospholanic rings set in adjacent positions of an aromatic pentatomic heterocycle.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Synthetic Route of 6287-82-7, Catalysts function by providing an alternate reaction mechanism that has a lower activation energy than would be found in the absence of the catalyst. In some cases, the catalyzed mechanism may include additional steps.In a article, 6287-82-7, molcular formula is C8H4Br2S, introducing its new discovery.

A series of highly sensitive neutral photoacid generators (PAGs) based on photochromic terarylenes was prepared. Like the example presented herein, these compounds show a subsequent thermal elimination of a Br°nsted acid after a light-triggered 6pi-electrocyclization, concomitant with the hexatriene aromatization. A novel type of molecular systems was developed, in which one thiazolyl moiety was replaced by a thienyl group. Depending on the solvents and on the nature of the acid source, the quantum yield (QY) for acid generation could reach up to 0.6. Comparative studies on the acid source clearly showed that aromatic leaving groups tend to extinguish the molecular system photoefficiency. A second type was also prepared, in which the nature of the hetero-aromatic rings were identical to our previous example, but their sequence was modified. Therefore, a second level of improvement was achieved in nonpolar solvents, pushing the QY value up to 0.7. Finally, we demonstrated the mesylic acid-releasing PAG as a photocatalyst in a chemically amplified positive resist system.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

A new application about 2,3-Dibromobenzo[b]thiophene

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Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction by binding to a specific portion of an enzyme and thus slowing or preventing a reaction from occurring.Formula: C8H4Br2S, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 6287-82-7, Name is 2,3-Dibromobenzo[b]thiophene, molecular formula is C8H4Br2S

Three new heteropentacene derivatives based on bis(benzothieno)silole were synthesized. The XRD characterization reveals that the crystal structures of the heteropentacenes can be significantly influenced by the methyl substitution. The optical and electrochemical properties were investigated and the experimental results confirm that the silole motif lowers the LUMO level of the heteropentacenes. Preliminary results show that the insertion of silole ring systems into rigid heteropentacenes leads to an improved solubility and high fluorescence quantum yield up to 0.74 in solution, which indicates the potential of these new silole-containing compounds for photonic and photoelectric applications. The strong and sensitive fluorescence quenching behavior towards picric acid (PA) demonstrates that the silole-containing heteropentacene derivatives are also promising fluorescent sensor materials for detecting the nitro-containing explosives. This journal is

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

Brief introduction of 2,3-Dibromobenzo[b]thiophene

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Described are the syntheses of substituted enediynes and dialkynylaromatics using Pd- or Pd/Cu-catalyzed cross coupling procedures. The products were then thermalized to afford the corresponding poly(p- phenylene)s, poly(1,4-naphthalene)s, poly(benzo[c]thiophene)s, and poly(dibenzothiophene)s. Fifteen examples are provided that show the scope of the polymerization process based upon substituent patterns and cyclization moieties. The superb thermal resiliency of the newly derived polymers is demonstrated using thermogravimetric analysis. The polymer structure was generally confirmed using IR data correlations to small molecules that resembled the polymers’ repeat unit structure. Radical trapping of dimeric intermediates, that were analyzed by GCMS, further substantiated the proposed mechanistic route. The step-growth polymerization pattern was determined by monitoring the degree of monomer consumption versus the polymer molecular weight.

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Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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6287-82-7, Name is 2,3-Dibromobenzo[b]thiophene, belongs to benzothiophene compound, is a common compound. SDS of cas: 6287-82-7In an article, once mentioned the new application about 6287-82-7.

A series of 2,3-diaryldibenzo[b]thiophene derivatives have been synthesized via Suzuki coupling reactions in moderate to good yields (59?79%). The synthesized compounds were evaluated for their antithrombolytic, biofilm inhibition, and hemolytic potential. All compounds showed significant biological potential. Compound (4k) revealed excellent antithrombolytic (87.24%) and biofilm inhibition (99.64%) activity. While compound (4i) exhibited an outstanding hemolytic potential (84.53%). The docking studies uncovered that studied compounds interact with streptokinase and plasminogen via hydrogen bonding, pi-anion, pi?pi stacked interactions, and pi-sigma bonding type interactions. The results revealed that synthesized benzo[b]thiophene derivatives could be a potential source of therapeutic agents.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

Simple exploration of C8H4Br2S

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5,6,7,8,9,10-Hexahydro-6,9-methanobenzocyclo-octen-11-one (3) was prepared through condensation of o-xylene-alpha,alpha’-diyl dibromide with N-cyclopentylidenepyrrolidine and converted by Beckmann rearrangement of its oxime (4) into 2,3,5,6-tetrahydro-2,5-ethano-3-benzazocin-4(1H)-one (6). 2,3-Bis(bromomethyl)benzothiophene was converted similarly into a mixture of 1,4,5,6-tetrahydro-2,5-ethano<1>benzothieno<2.3-d>azocin-3(2H)-one (15) and the isomeric lactam (19).Lactam (6) was N-methylated and both the parent lactam (6) and the N-methyl derivative (23) were reducedwith lithium aluminium hydride to the saturated products (24) and (25), respectively.Conversion of lactam (6) into the corresponding thiolactam (26) with phosphorus pentasulphide followed by alkylation of the latter compound gave an N-(29) or S-alkylated derivative, (27) or (28), depending on the reagent and reaction conditions.Similar reactions are reported also for lactams (15) and (19).The 4(1H)-one structures of compounds (15) – (22) are based on an X-ray analysis of 3-methyl-2,3,5,6-tetrahydro-2,5-ethano<1>benzothieno<3,2-d>azocin-4(1H)-one (20).We also report syntheses of 2-azido-5,6,7,8,9,10-hexahydro-6,9-methanobenzocyclo-octen-11-one (33) and 3-nitro(and 1,3-dinitro)-6,7,8,9,10,11-hexahydro-7,10-methanocyclo-octa<1>benzothiophen-12-one, (36) and (37), respectively.

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

 

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Straightforward syntheses leading to pi-extended benzosilolothiophene (BST) derivatives by Rh-catalyzed dehydrogenative cyclization reactions have been developed. Electron-deficient ligands were effective for the reactions, and dppe-F20 gave the best result. This method could be applied to the synthesis of highly pi-extended ladder-type BST derivatives, which exhibited fluorescence.

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Benzothiophene – Wikipedia,
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The combination of the recently developed multicomponent construction of highly substituted 3,4-dihydropyridones with subsequent allylation and intramolecular Heck-type cyclization allows the straightforward construction of benzo[a]quinolizines, a class of polycyclic compounds that- despite their interesting pharmacological and photochemical properties- have little precedent in the literature. After optimization of the individual steps, we used this reliable three-step sequence to generate a small library of diversely substituted benzo[a]quinolizines and various heterocyclic analogs. Copyright

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Reference:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem