Properties and Exciting Facts About 2,3-Dibromobenzo[b]thiophene

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HETERO-CYCLIC COMPOUND AND ORGANIC LIGHT EMITTING DEVICE USING THE SAME

The organic application of prolonging the life, efficiency, markedly improves the electrochemical stability and thermal stability can be heterocyclic compound, and said heterocyclic compound contained in the organic compound layer organic light emitting device number under public affairs substrate. (by machine translation)

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Benzothiophene – Wikipedia,
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New explortion of 2,3-Dibromobenzo[b]thiophene

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An efficient novel synthesis of beta-(azuleno[1,2-b]benzothienyl)-and beta-(azuleno[2,1-b]benzothienyl)-alpha,beta-unsaturated ketones by the tropylium ion-mediated intramolecular furan ring-opening reaction and X-ray investigation of methyl ketone derivative

Intramolecular reaction of 2-tropylio-3-(5-substituted 2-furyl) benzothiophenes (3), prepared from the corresponding 2-cycloheptatrienyl-3-(5- substituted 2-furyl)benzothiophenes (2), afforded the beta-(azuleno[1,2-b] benzothienyl)-alpha,beta-unsaturated ketones (4), which are otherwise difficult to obtain, in moderate yields. The reaction involves a ring-opening process of the furan ring by intramolecular attack of the tropylium ion onto the 2-position of the furan ring. Similarly, beta-(azuleno[2,1-b]benzothienyl)- alpha,beta-unsaturated ketones (8) were obtained from the corresponding 3-tropylio-2-(5-substituted 2-furyl)benzothiophenes (7) albeit in lower yields. The molecular and crystal structures of the methyl ketone derivative, 8a, are discussed on the basis of X-ray structure analysis.

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Extended knowledge of C8H4Br2S

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Ligand cooperation in the formal hydrogenation of N2O using a PCsp2P iridium pincer complex

A new PCcarbeneP pincer ligand with 2,3-benzo[b]thiophene linkers connecting the flanking dialkyl phosphine donors to the central carbene can be attached to Ir(I). The chloro derivative reacts with N2O with loss of N2 to form an iridaepoxide species by addition of an oxygen atom to the Ir=C linkage. This compound reacts with H2 to afford the oxidative addition product, in which the hydride ligands are trans to the Ir-O bond. Heating this dihydride results in slow release of H2O; kinetic and spectroscopic studies show that conversion of the dihydride to its isomer, in which the hydrides are cis to the Ir-O bond, is required for H2O elimination to take place. Together, these reactions constitute the stoichiometric conversion of N2O and H2 to N2 and H2O; further mechanistic studies suggest ways to make the system catalytic.

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Some scientific research about 2,3-Dibromobenzo[b]thiophene

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Self-Contained Photoacid Generator Triggered by Photocyclization of Triangle Terarylene Backbone

We herein propose a new type of efficient neutral photoacid generator. A photoinduced 6pi-electrocyclization reaction of photochromic triangle terarylenes triggers subsequent release of a Br¡ãnsted acid, which took place from the photocyclized form. A H-atom and its conjugate base were introduced at both sides of a 6pi-system to form the self-contained photoacid generator. UV irradiation to the 6pi-system produces a cyclohexa-1,3-diene part with a H-atom and a conjugate base on the sp3 C-atoms at 5- and 6-positions, respectively, which spontaneously release an acid molecule quantitatively forming a polyaromatic compound. A net quantum yield of photoacid generation as high as 0.52 under ambient conditions and a photoinitiated cationic polymerization of an epoxy monomer are demonstrated.

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Synthesis of 2,3-disubstituted benzo[b]thiophenes via palladium-catalyzed coupling anphilic cyclization of terminal acetylenes

2,3-Disubstituted benzo[b]thiophenes have been prepared in excellent yields via coupling of terminal acetylenes with commercially available o-iodothioanisole in the presence of a palladium catalyst and subsequent electrophilic cyclization of the resulting o-(1-alkynyl)thioanisole derivatives. I2, Br2, NBS, p-O2NC6H4SCl, and PhSeCl have been utilized as electrophiles. Aryl-, vinyl-, and alkyl-substituted terminal acetylenes undergo this coupling and cyclization to produce excellent yields of benzo[b]thiophenes. (Trimethylsilyl)acetylene also undergoes this coupling/cyclization process with I2, NBS, and the sulfur and selenium electrophiles to afford the corresponding 2-(trimethylsilyl)-benzo[b]thiophenes. However, cyclization of the silyl-containing thioanisole using Br2 affords 2,3-dibromobenzo[b]thiophene.

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Benzothiophene – Wikipedia,
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Awesome Chemistry Experiments For 2,3-Dibromobenzo[b]thiophene

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BENZOTHIOPHENE DERIVATIVES AND ORGANIC ELECTROLUMINESCENT DEVICES USING THE SAME

The present invention relates to a compound represented by following general formula (I): wherein R1 and R2 are independently selected from a substituted or unsubstituted C4 to C30 arylamine group, a substituted or unsubstituted C4 to C40 carbazole group, a substituted or unsubstituted C4 to C40 benzothiophene group or a substituted or unsubstituted C4 to C40 benzofuran group; L is a bridging group, and selected from a single bond substituted C4 to C40 arylamine group, a substituted C4 to C40 carbazole group, a substituted C4 to C40 benzothiophene group, O atom, N atom or S atom; R3-R10 are independently selected from H atom, a C1-C20 aliphatic compound containing linear or branched alkanes, alkenes or alkynes or a C6-C30 aromatic group, or two adjacent groups linking to be a ring forming a naphthothiophene derivatives; m and n are selected from integers of 1 to 3, as well as the addition of m and n is larger than 0 but less than or equal to 3. Also, the present invention relates to organic electroluminescent devices using the compound represented by general formula (I), especially a hole transporting material, a hole injecting material or a main material of organic luminescent material used in an OLED device.

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Benzothiophene – Wikipedia,
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Awesome Chemistry Experiments For C8H4Br2S

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Enhanced performance of benzothieno[3,2-b]thiophene (BTT)-based bottom-contact thin-film transistors

Three new benzothieno[3,2-b]thiophene (BTT; 1) derivatives, which were end-functionalized with phenyl (BTT-P; 2), benzothiophenyl (BTT-BT; 3), and benzothieno[3,2-b]thiophenyl groups (BBTT; 4; dimer of 1), were synthesized and characterized in organic thin-film transistors (OTFTs). A new and improved synthetic method for BTTs was developed, which enabled the efficient realization of new BTT-based semiconductors. The crystal structure of BBTT was determined by single-crystal X-ray diffraction. Within this family, BBTT, which had the largest conjugation of the BTT derivatives in this study, exhibited the highest p-channel characteristic, with a carrier mobility as high as 0.22 cm2 V-1 s-1 and a current on/off ratio of 1¡Á10 7, as well as good ambient stability for bottom-contact/bottom-gate OTFT devices. The device characteristics were correlated with the film morphologies and microstructures of the corresponding compounds. Copyright

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Final Thoughts on Chemistry for C8H4Br2S

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Large geometrical structure changes of photochromic diarylethenes upon photoirradiation

Photochromic diarylethene derivatives having phenylethynyl and pent-1-ynyl groups at the reactive carbons have been synthesized. These ethynyl groups enhance the cycloreversion quantum yields of diarylethenes without affecting the absorption maxima and the absorption coefficients of the closed-ring isomers. The derivatives exhibited large geometrical structural changes in the photoisomerization process.

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Extracurricular laboratory:new discovery of C8H4Br2S

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Benzo[b]thiophene-fused boron and silicon ladder acenes

Synthetic routes to three new heteroacene compounds in which two benzo[b]thienyl units are bridged by dimethylsilyl and/or mesitylboryl units are described. In the Si/Si and Si/B compounds 1-syn and 3-syn, respectively, the sulfur atoms of the flanking benzo[b]thiophenes are disposed in meta positions on the central six-membered heterocycle, while in the B/B compound 4-anti, they are para to each other; the reasons for this lie in the synthetic method employed to prepare 4-anti. All three compounds were crystallographically characterized and their photophysical properties examined. A comprehensive examination of their photophysical properties shows that they are weakly absorbing and fluorescing materials, with the diborin derivative 4-anti exhibiting the most red-shifted absorption maxima and largest fluorescence quantum yield.

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Brief introduction of C8H4Br2S

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10. The Diyne Reaction of 3,3?-Bis(phenylethynyl)-2,2?-bithiophene Derivatives via Rhodium Complexes: A Novel Approach to Condensed Benzo[2,1-b:3,4b’]dithiophenes

The syntheses of benzo-fused benzo[2,1-b:3,4-b’]dithiophenes 1 and benzo[2,1-b:3,4-b’:5,6-c?]trithiophenes 2 are described. The treatment of easily available 3,3?-bis(phenylethynyl)-2,2?-bithiophene derivatives 5a and 6 (via PdII-catalyzed alkynylation of the corresponding 3,3?-dibromo-2,2?-bithiophenes; see Scheme 1) with chlorotris(triphenylphosphine)rhodium(I) yields the corresponding cyclic rhodium complexes 7 (Scheme 2) which smoothly react with acetylenes and sulfur to give 1 and 2 in good yields (Schemes 3-5).

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Benzothiophene – Wikipedia,
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