Tran, Khoa M. published the artcileSynthesis of primary N-arylthioglyoxamides from anilines, elemental sulfur and primary C-H bonds in acetophenones, Name: 3-Acetylthiophene, the main research area is ketothioamide preparation; aniline sulfur aryl methyl ketone oxidative coupling.
A simple method for coupling of anilines, acetophenones and elemental sulfur to afford α-ketothioamides RNHC(S)C(O)R1 [R = cyclohexyl, Ph, 2-ClC6H4, etc.; R1 = 2-MeOC6H4, 3-BrC6H4, 2-thienyl, etc.] was developed. Reactions proceeded in the presence of Na2SO3 and DMSO, thus eliminating the need for transition metals and external oxidants. Functionalities such as halogen, ester, methylthio, and heterocycle groups were compatible with the conditions. Electron-poor acetophenones sometimes gave isosteric glyoxamides.
RSC Advances published new progress about Anilines Role: RCT (Reactant), RACT (Reactant or Reagent). 1468-83-3 belongs to class benzothiophene, name is 3-Acetylthiophene, and the molecular formula is C6H6OS, Name: 3-Acetylthiophene.
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem