Day: November 22, 2022

Photochromic reactivity induced by electron distribution: active or inactive was written by Li, Xiaochuan;Wang, Yaxin;Jia, Caixia;Kim, Hyorim;Son, Young-A.. And the article was included in Molecular Crystals and Liquid Crystals in 2019.COA of Formula: C6H8S The following contents are mentioned in the article:

Photochromic core structure, triangle terthiophene, is configured to the design of 2,3-Bis(2,5-dimethylthiophen)-5-methoxyphenylethynylthiophene (PT) and 2,3-Bis(2,5-dimethylthiophen)-5-(4-methoxyphenyl)-1,3-butadiene-1,1,4,4-tetracarbonitrile(MPT) and characterized by NMR and HRMS technol. The photochromic behavior is investigated in typical solvents. With in hexane, reversibly photochromic process is induced by alternative irradiation of UV and Visible light. The solution color of can be toggled between colorless and pink, forming a switch cycle. In chloroform, the photochromic wavelength moves to shorter wavelength side. For, UV light induced photochromism is not observed Due to the addition of tetracarbonitrile, its strong electron-withdrawing character significantly lowers the electron d. on reactive carbon atoms in LUMO, which is one of the key elements to support the photoactive of photochromism. Therefore, the mol. configuration of electron distribution is important to the design of photochromic dyes. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8COA of Formula: C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.COA of Formula: C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Desulfurization of hexyl sulfide and hexanethiol using supercritical water was written by Kang, Jimoon;Sim, Seungjae;Jung, Hyunwook;Han, Byungchan;Lee, Youn-Woo. And the article was included in Journal of Supercritical Fluids in 2020.Synthetic Route of C6H8S The following contents are mentioned in the article:

Desulfurization of hexyl sulfide and hexanethiol using supercritical water (SCW) was investigated by combining exptl. and computational methods to study the desulfurization of alkyl sulfides and thiols in SCW. Desulfurization was conducted for 0 ∼ 30 min at 400°C using thermal decomposition and SCW decomposition (24.7 ∼ 25.6 MPa), and the reaction pathways were built using the automated Reaction Mechanism Generator (RMG) and Gaussian 09. In thermal decomposition, C6-hydrocarbons (hexane, hexene) are main products, but in SCW, C5-hydrocarbon (pentane) in addition to C6-hydrocarbons are main products with higher alkane to alkene ratio. For the reaction pathways, in SCW, water participates as catalysts and reactants donating hydrogens with inhibited production of cyclic sulfides while in thermal decomposition, the hydrogen was deficient producing aromatic sulfur compounds such as thiophenes and alkyl-thiacycloalkanes. This study is expected to clarify the decomposition reactions of alkyl sulfides and alkyl thiols in SCW. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Synthetic Route of C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is a fused ring compound of thiophene ring and benzene ring, which is an important class of heterocycles with advantageous structures. Its aromaticity makes it relatively stable, although as a heterocycle, it has reactive sites which allow for functionalization.Synthetic Route of C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Synthesis and application of near-infrared dyes based on sulfur-substituted dicyanomethylene-4H-chromene and diarylethene was written by Wang, Yuesong;Yu, Haoli;Chen, Yan;Cui, Mengyuan;Ji, Min. And the article was included in New Journal of Chemistry in 2022.Safety of 2,5-Dimethylthiophene The following contents are mentioned in the article:

Four novel compounds (S-DCM-1O, S-DCM-2O, S-DCM-3O, and S-DCM-4O) based on sulfur-substituted dicyanomethylene-4H-chromene (S-DCM) and diarylethene were synthesized. The detailed investigations on the fluorescence spectra, absorption spectra, and time-dependent d. functional theory calculations (DFT/TD-DFT) were presented. The encapsulation of mPEG2000-DSPE effectively increased the solubility of all the as-prepared samples. The results of TEM showed that the nanoparticles had a good dispersion coefficient All the nanomaterials (S-DCM-1O@PEG, S-DCM-2O@PEG, S-DCM-3O@PEG, and S-DCM-4O@PEG) exhibited near-IR emission (650-900 nm) and thus reduced light damage and light scattering for cell imaging in biol. applications. Furthermore, PLL (poly-L-lysine hydrobromide) was used to modify the surface of nanoparticles to facilitate easy uptake by A549 cells by changing their electronegativity. The results suggested that S-DCM-2O@PEG@PLL was a highly suitable candidate for cell imaging because of its low toxicity and excellent biocompatibility. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Safety of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. It is also used in the manufacturing of dyes such as thioindigo.Safety of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Diverse Reactions of Thiophenes, Selenophenes, and Tellurophenes with Strongly Oxidizing I(III) PhI(L)₂ Reagents was written by Egalahewa, Sathsara;Albayer, Mohammad;Aprile, Antonino;Dutton, Jason L.. And the article was included in Inorganic Chemistry in 2017.Safety of 2,5-Dimethylthiophene The following contents are mentioned in the article:

The authors report the outcomes of the reactions of aromatic group 16 thiophene, selenophene, and tellurophene rings with the I(III) oxidants PhI(OAc)(OTf) and [PhI(Pyr)₂][OTf]₂ (Pyr = pyridine). In all reactions, oxidative processes take place, with generation of PhI as the reduction product. However, with the exception of tellurophene with PhI(OAc)(OTf), +4 oxidation state complexes are not observed, but rather a variety of other processes occur. In general, where a C-H unit is available on the 5-membered ring, an electrophilic aromatic substitution reaction of either -IPh or pyridine onto the ring occurs. When all positions are blocked, reactions with PhI(OAc)(OTf) give acetic and triflic anhydride as the identifiable oxidative byproducts, while [PhI(Pyr)₂][OTf]₂ gives pyridine electrophilic aromatic substitution onto the peripheral rings. Qual. mechanistic studies indicate that the presence of the oxidizable heteroatom is required for pyridine to act as an electrophile in a substantial manner. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Safety of 2,5-Dimethylthiophene).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. It is found within the chemical structures of pharmaceutical drugs such as zileuton, raloxifene, and sertaconazole, and also BTCP.Safety of 2,5-Dimethylthiophene

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Efficient Synthesis of Bis(dibromomethyl)arenes as Important Precursors of Synthetically Useful Dialdehydes was written by Bodzioch, Agnieszka;Owsianik, Krzysztof;Skalik, Joanna;Kowalska, Emilia;Stasiak, Anna;Rozycka-Sokolowska, Ewa;Marciniak, Bernard;Balczewski, Piotr. And the article was included in Synthesis in 2016.Electric Literature of C6H8S The following contents are mentioned in the article:

This work presents an efficient synthesis of bis(dibromomethyl)benzenes and a bis(dibromomethyl)thiophene as precursors of aromatic dialdehydes by bromination of dimethyl-substituted arenes under various reaction conditions (yields up to 99%). Several new variants of this reaction, including the use of N-bromosuccinimide (NBS) and bromine, and various solvents to replace carbon tetrachloride, benzene and carbon disulfide, were also tested. In the optimized protocols, the inconvenient solvents were replaced by 1,2-dichloroethane (DCE) and/or acetonitrile. In the DCE protocols, we reduced reaction times 24-32-fold, reduced the amount of NBS a few-fold and lowered power consumption relative to the literature protocols. The procedures also allowed elimination of long-lasting incandescent irradiation (100-500 W). The replacement of NBS by bromine led to a further reduction in the amount of brominating agent. The obtained bromo derivatives were efficiently converted into the corresponding dialdehydes (90-96%), which in turn are useful in materials chem. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Electric Literature of C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophenes are valuable heterocycles that are widely used in medicines, agrochemicals, and materials science. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Electric Literature of C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Characterization of the volatile organic compounds produced from avocado during ripening by gas chromatography ion mobility spectrometry was written by Liu, Yijun;Bu, Mengting;Gong, Xiao;He, Jinna;Zhan, Yu. And the article was included in Journal of the Science of Food and Agriculture in 2021.Product Details of 638-02-8 The following contents are mentioned in the article:

BACKGROUND : The volatile organic compounds (VOCs) produced from avocados during storage may be distinct at different periods, and this difference may be related to their degree of maturity, for which no relevant research has been conducted yet. RESULTS : A total of 30 typical target compounds were identified by gas chromatog.-ion mobility spectrometry (GC-IMS) combined with principal component anal. (PCA) for the VOCs produced during the post-harvesting process of avocado. With an increase in storage time, the VOCs content produced by avocado due to ripening continued to increase, and the uptrend was particularly obvious on day 13. The storage time of avocado could be distinguished according to the PC1 and PC2 values in the PCA chart. Conclusion : GC-IMS detection combined with PCA was used to establish the fingerprints of VOCs in avocado for the first time. The maturity of avocados was determined by identifying the signal strength of characteristic VOCs, and this method could be of great potential to predict the maturity of fruits in the future. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Product Details of 638-02-8).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is relatively a stable molecule. The electrophilic substitution of benzothiophene systems is much less regioselective than that of indoles. Its aromaticity makes it relatively stable, although as a heterocycle, it has reactive sites which allow for functionalization.Product Details of 638-02-8

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Characterization of the key aroma compounds in mulberry fruits by application of gas chromatography-olfactometry (GC-O), odor activity value (OAV), gas chromatography-mass spectrometry (GC-MS) and flame photometric detection (FPD) was written by Zhu, JianCai;Wang, LingYing;Xiao, ZuoBing;Niu, YunWei. And the article was included in Food Chemistry in 2018.Formula: C6H8S The following contents are mentioned in the article:

The volatile compounds of mulberries obtained from three cultivars (M. nigra, Y1, M. Macroura, Y2 and M. Alba, Y3) were investigated by gas chromatog.-olfactometry (GC-O), odor activity value (OAV), gas chromatog.-mass spectrometry (GC-MS) and flame photometric detection (FPD). The results showed that 41, 37 and 41 compounds were detected in Y1, Y2 and Y3 samples, resp. In addition, 12, 11, and 12 sulfur compounds were identified in three samples by FPD, resp. Quant. anal. showed 2-(methylthio)ethanol, methionol, di-Me sulfide, methional and 3-ethylthiophene were present in relatively high amounts in each of the three samples. Furthermore, benzaldehyde, Et butanoate, (E)-2-nonenal, 1-hexanol, hexanal, methional, 3-mercaptohexyl acetate and 3-mercaptohexanol were present with much higher OAVs than other compounds Finally, four compounds (pentanal, Et acetate, acetic acid, methionol) were selected to investigate possible effects on six descriptors, which indicated that the volatile compounds at sub-threshold concentrations are likely to contribute to overall aroma. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Formula: C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is relatively a stable molecule. The core structure is a part of various pharmaceutical substances and natural products. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Formula: C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Light-Responsive Pyrazine-Based Systems: Probing Aromatic Diarylethene Photocyclization was written by Milic, Jovana V.;Schaack, Cedric;Hellou, Nora;Isenrich, Florin;Gershoni-Poranne, Renana;Neshchadin, Dmytro;Egloff, Sylvain;Trapp, Nils;Ruhlmann, Laurent;Boudon, Corinne;Gescheidt, Georg;Crassous, Jeanne;Diederich, Francois. And the article was included in Journal of Physical Chemistry C in 2018.Reference of 638-02-8 The following contents are mentioned in the article:

Here, we present an investigation of the photocyclization of novel aromatic diarylethene (DAE) systems 1-3 based on pyrazine, quinoxaline, and helicene scaffolds. These prospective photoswitches were designed using d. functional theory calculations and analyzed in solution and in the solid state by cyclic and rotating disk voltammetry, UV visible and transient absorption spectroscopy, as well as X-ray crystallog. Addnl., nucleus-independent chem. shift calculations were performed to investigate the influence of aromaticity on the photocyclization ability. While pyrazine-2,3-diyl-extended DAE system 1 demonstrated photoswitching ability with short lifetimes of the cyclized form, the more aromatic quinoxaline analog 2 did not feature any photocyclization. Further extension of these aromatic systems into helicene-DAE 3 resulted in the stabilization of the cyclized form through the conserved backbone aromaticity, accompanied by enhanced photochromism. This study paves the way toward the generation of aromatic DAE photoswitches for light-controlled mol. systems in the future. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Reference of 638-02-8).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene scaffolds are of great importance due to its increased presence in bioactive molecules. The different substitution patterns in these heterocycles offer new opportunities for drug discovery and other applications in materials science.Reference of 638-02-8

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Interface engineering of quaternary ammonium phosphotungstate for efficient oxidative desulfurization of high-sulfur petroleum coke was written by Gong, Jiahong;Xu, Huanhuan;Liu, Jixing;Liu, Hui;Hua, Mingqing;Yang, Ning;Wu, Peiwen;Li, Huaming;Zhu, Wenshuai. And the article was included in Petroleum Science and Technology.Formula: C6H8S The following contents are mentioned in the article:

Reducing the sulfur content in high-sulfur petroleum coke (HSPC) has become an urgent issue, however, remains a great challenge with the development of petroleum refining industry. Herein, a highly-efficient catalyst quaternary ammonium phosphotungstate ionic liquid [(C4H9)4N]3PW12O40 (C4@HPA) was initiated to activate H2O2, and the sulfur content of HSPC was remarkably decreased from 4.46 weight% to 2.76 weight% at a relatively mild temperature (70 oC), which is discernible below than 1400 oC in industry. The characterization results showed that only sulfate can be removed, while sulfoxide and sulfone were retained in petroleum coke. Moreover, the desulfurization activity of C4@HPA/H2O2 to thiophene sulfides decreases as follows: Thiophene > 2-Methylthiophene > 2,5-Dimethylthiophene > Dibenzothiophene > 4-Methyldibenzothiophene. It reveals that the sulfur of 4-MDBT is the most difficult to be removed. Therefore, this founding here may shine light on the understanding and construction of efficient catalyst for desulfurization of high-sulfur petroleum coke in industry. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Formula: C6H8S).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is relatively a stable molecule. The core structure is a part of various pharmaceutical substances and natural products. Due to its aromaticity, thiophenes do not exhibit the same properties as conventional thioethers.Formula: C6H8S

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem

Reactions of a 3-phenyl-1-trifluoromethyl-prop-2-yne iminium salt with furans, thiophenes, and pyrroles was written by Schneider, Thomas;Heinrich, Georg;Koch, Raphael;Maas, Gerhard. And the article was included in European Journal of Organic Chemistry in 2021.Recommanded Product: 638-02-8 The following contents are mentioned in the article:

Reactions of a novel propyne iminium salt, N,N-di-Me 3-phenyl-1-trifluoromethyl-propyne iminium triflate, with electron-rich heteroaromatic ring systems (furans, thiophenes, pyrroles) are reported. The 1-CF₃-propyne iminium ion can act as a highly reactive ambident electrophile, giving rise to simple electrophilic heteroaromatic ring substitution products, and as a 1,3-biselectrophile leading to C₂+C₃-CF₃ annulation products. Moreover, it is an electron-deficient alkyne which was found to afford double [2+2] cycloaddition products with 2,5-dimethylfuran and 2,5-dimethylthiophene. The obtained mol. structures include CF₃-containing compounds with cyclopenta[b]furan, cyclopenta[b]thiophene, cyclopenta[c]thiophene, cyclopenta[b]pyrrole, cyclopenta[c]pyrrole, 3H-pyrrolizine, and 1,4-dihydrocyclopenta[b]pyrrole ring systems. Analogous reactions of 1,3(or 1,4)-phenylenebis(1-CF₃-propyne iminium) salts with furans, pyrroles or thiophenes in a 2 : 1 stoichiometry lead to phenylene-tethered condensed heterocycles of the same type. This study involved multiple reactions and reactants, such as 2,5-Dimethylthiophene (cas: 638-02-8Recommanded Product: 638-02-8).

2,5-Dimethylthiophene (cas: 638-02-8) belongs to benzothiophene derivatives. Benzothiophene is a fused ring compound of thiophene ring and benzene ring, which is an important class of heterocycles with advantageous structures. It is also used in the manufacturing of dyes such as thioindigo.Recommanded Product: 638-02-8

Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem