Zhuang, Shi-Yi published the artcileCopper-catalyzed Reaction of Anthranils with Methyl Ketones: Site-Selective C5-Dicarbonylation of Anthranils, Synthetic Route of 1468-83-3, the main research area is diketone preparation regioselective; anthranil aryl methyl ketone dicarbonylation copper catalyst.
A copper-catalyzed site-selective C5-dicarbonylation reaction of 2,1-benzisoxazole has been developed for synthesis of 1,2-dicarbonyl compounds RC(O)C(O)R1 (R = C6H5, 4-FC6H4, 2-thienyl, etc.; R1 = 4-amino-3-formylphenyl) using Me ketones RC(O)Me as a com. available carbonylation reagent. This process represents the first example to implement the C5-dicarbonylation of anthranils, which involves an oxidative Csp3-H/Csp2-H cross-coupling reaction along with thermolytic N-O bond cleavage.
Advanced Synthesis & Catalysis published new progress about Alkyl aryl ketones Role: RCT (Reactant), RACT (Reactant or Reagent). 1468-83-3 belongs to class benzothiophene, name is 3-Acetylthiophene, and the molecular formula is C6H6OS, Synthetic Route of 1468-83-3.
Referemce:
Benzothiophene – Wikipedia,
Benzothiophene | C8H6S – PubChem